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732 1 1. The exact age at which they are first de- tectable, and the pattern in which they develop, is depen- dent on the specific receptor or peptide. 48 eV for first ionisation potentials rSterically crowded molecules appear too unstable rFour-membered rings appear too stable rHypercoordinate compounds appear too unstable rNonclassical structures normally appear too unstable Currenxy with corresponding classical structures rRotational barriers are often underesti- mated rHydrogen bonds appear too weak and too long rCalculated activation barriers are typically somewhat too high rPericyclic reactions: biradicaloid mechanisms favoured.

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